Altmetric

An Insight on the Effect of Azobenzene Functionalities Studied in UiO-66 Framework for Low Energy CO2 Capture and CO2/N2 Membrane Separation

Title: An Insight on the Effect of Azobenzene Functionalities Studied in UiO-66 Framework for Low Energy CO2 Capture and CO2/N2 Membrane Separation
Authors: Prasetya, N
Ladewig, B
Item Type: Dataset
Abstract: Data supporting journal manuscript. Includes an Excel spreadsheet with all the raw data for the figures in the manuscript, calibrations and calculations. Also includes 3D chemical structures of MOF units, and SEM images of MOF/polymer composite materials. Abstract In this paper, we report a simple approach to study the fundamental aspect of light-responsive metal organic framework (MOF) in UiO-66 topology through a mixed-ligand approach. Apart from change in the structural property, the loading of azobenzene linker inside the framework also affects the CO2 light-responsive property and CO2/N2 selectivity which could help to design future low-energy CO2 adsorbents. Further study to incorporate the MOFs into mixed matrix membranes also indicates the benefit of higher azobenzene loading in the MOF to enhance the CO2/N2 separation performance since it can improve the separation performance which could not be obtained in non-functionalized fillers.
Data supporting journal manuscript. Includes an Excel spreadsheet with all the raw data for the figures in the manuscript, calibrations and calculations. Also includes 3D chemical structures of MOF units, and SEM images of MOF/polymer composite materials. Abstract In this paper, we report a simple approach to study the fundamental aspect of light-responsive metal organic framework (MOF) in UiO-66 topology through a mixed-ligand approach. Apart from change in the structural property, the loading of azobenzene linker inside the framework also affects the CO2 light-responsive property and CO2/N2 selectivity which could help to design future low-energy CO2 adsorbents. Further study to incorporate the MOFs into mixed matrix membranes also indicates the benefit of higher azobenzene loading in the MOF to enhance the CO2/N2 separation performance since it can improve the separation performance which could not be obtained in non-functionalized fillers.
Content Version: 1
Issue Date: 8-Jan-2019
URI: http://hdl.handle.net/10044/1/65851
DOI: https://doi.org/10.5281/zenodo.2533853
Copyright Statement: http://creativecommons.org/licenses/by/4.0/legalcode
Keywords: metal organic framework
light responsive
gas permeation
azobenzene
membrane
carbon dioxide seperation
carbon capture
Appears in Collections:Faculty of Engineering - Research Data