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3D mapping of gas physisorption for the spatial characterisation of nanoporous materials
File | Description | Size | Format | |
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Joss_ChemPhysChem_2018_upload.pdf | Accepted version | 1.59 MB | Adobe PDF | View/Open |
Title: | 3D mapping of gas physisorption for the spatial characterisation of nanoporous materials |
Authors: | Joss, L Pini, R |
Item Type: | Journal Article |
Abstract: | Nanoporous materials used in industrial applications (e.g., catalysis and separations) draw their functionality from properties at the nanoscale (1 – 10 Å). When shaped into a technical form these solids reveal spatial variations in the same properties over much larger length scales (1 µm – 1 cm). The multiscale characterization of these systems is impaired by the trade‐off between sample size and image resolution that is bound to the use of most imaging techniques. We show here the application of X‐ray computed tomography for the non‐invasive spatial characterization of a zeolite/activated carbon adsorbent bed across three orders of magnitude in scale. Through the unique combination of gas adsorption isotherms measured locally and their interpretation by physisorption analysis, we determine three‐dimensional maps of the specific surface area and micropore volume. We further use machine learning to identify and locate the materials within the packed bed. This novel ability to reveal the extent of heterogeneity in technical porous solids will enable a deeper understanding of their function in industrial reactors. Such developments are essential towards bridging the gap between material research and process design. |
Issue Date: | 18-Feb-2019 |
Date of Acceptance: | 13-Dec-2018 |
URI: | http://hdl.handle.net/10044/1/65113 |
DOI: | https://dx.doi.org/10.1002/cphc.201801148 |
ISSN: | 1439-4235 |
Publisher: | Wiley |
Start Page: | 524 |
End Page: | 528 |
Journal / Book Title: | ChemPhysChem |
Volume: | 20 |
Issue: | 4 |
Copyright Statement: | © 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is the accepted version of the following article: Joss, L. and Pini, R. (2018), 3D mapping of gas physisorption for the spatial characterisation of nanoporous materials. ChemPhysChem. Accepted Author Manuscript., which has been published in final form at https://dx.doi.org/10.1002/cphc.201801148 |
Sponsor/Funder: | Qatar Shell Research and Technology Center QSTP LLC |
Funder's Grant Number: | 490000724 |
Keywords: | Science & Technology Physical Sciences Chemistry, Physical Physics, Atomic, Molecular & Chemical Chemistry Physics adsorption gas physisorption machine learning porous materials X-ray computed tomography SWING ADSORPTION CARBON-DIOXIDE CO2 CAPTURE ISOTHERMS KINETICS RECOVERY STORAGE TIME N-2 H-2 X-ray computed tomography adsorption gas physisorption machine learning porous materials Chemical Physics 0306 Physical Chemistry (incl. Structural) 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics 0307 Theoretical and Computational Chemistry |
Publication Status: | Published |
Online Publication Date: | 2018-12-13 |
Appears in Collections: | Chemical Engineering Faculty of Engineering |