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Absence of Ni on the outer surface of Sr doped La2NiO4 single crystals

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Energy & Environmental Science_2013.docxAccepted version2.53 MBMicrosoft WordView/Open
Energy & Environmental Science_2013_Figures.docxSupporting information439.56 kBMicrosoft WordView/Open
Title: Absence of Ni on the outer surface of Sr doped La2NiO4 single crystals
Authors: Burriel, M
Wilkins, S
Hill, JP
Muñoz-Márquez, MA
Brongersma, HH
Kilner, JA
Ryan, MP
Skinner, SJ
Item Type: Journal Article
Abstract: A combination of surface sensitive techniques was used to determine the surface structure and chemistry of La2−xSrxNiO4+δ. These measurements unequivocally showed that Ni is not present in the outermost atomic layer, suggesting that the accepted model with the B-site cations exposed to the environment is incorrect.
Issue Date: 1-Jan-2014
Date of Acceptance: 4-Nov-2013
URI: http://hdl.handle.net/10044/1/13828
DOI: 10.1039/C3EE41622D
ISSN: 1754-5692
Publisher: Royal Society of Chemistry
Start Page: 311
End Page: 316
Journal / Book Title: Energy and Environmental Science
Volume: 7
Issue: 1
Copyright Statement: © The Royal Society of Chemistry 2014
Sponsor/Funder: Kaust UK Ltd
Funder's Grant Number: N/A
Keywords: Science & Technology
Physical Sciences
Technology
Life Sciences & Biomedicine
Chemistry, Multidisciplinary
Energy & Fuels
Engineering, Chemical
Environmental Sciences
Chemistry
Engineering
Environmental Sciences & Ecology
OXYGEN DIFFUSION
TRANSPORT-PROPERTIES
LA2-XSRXNIO4+DELTA
OXIDES
ADSORPTION
SYSTEM
Energy
Notes: http://pubs.rsc.org/en/journals/journalissues/ee#!recentarticles&am
Publication Status: Published
Appears in Collections:Materials
Faculty of Natural Sciences
Faculty of Engineering