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Bis(σ-B-H) complexes of copper(i): precursors to a heterogeneous amine-borane dehydrogenation catalyst
File(s)
Dalton.docx (4.76 MB)
Accepted version
c5dt02144h.pdf (827.95 KB)
Published version
Author(s)
Nako, AE
White, AJ
Crimmin, MR
Type
Journal Article
Abstract
A series of bis(σ-B-H) complexes of copper(i) have been prepared by displacement of arene solvent from a β-diketiminate copper(i) complex by four-coordinate boranes, H3B-L (L = NMe3, lutidine). In the presence of the same copper arene complex, the secondary amine-borane H3B-NMe2H undergoes dehydrogenation. We provide evidence for formation of a heterogengous catalyst from decomposition of the solution species.
Date Issued
2015-06-17
Date Acceptance
2015-06-17
Citation
Dalton Transactions, 2015, 44, pp.12530-12534
URI
DOI
ISSN
1477-9226
Publisher
Royal Society of Chemistry
Start Page
12530
End Page
12534
Journal / Book Title
Dalton Transactions
Volume
44
Copyright Statement
© The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. (CC BY)
Publication Status
Published