Long-term solar water and CO2 splitting with photoelectrochemical BiOI-BiVO4 tandems
File(s)BiOI_PEC_SI_final.docx (14.96 MB) BiOI_PEC_main_final.docx (77.83 KB)
Accepted version
Accepted version
Author(s)
Type
Journal Article
Abstract
Photoelectrochemical (PEC) devices have been developed for direct solar fuel production, but the limited stability of submerged light absorbers hampers their commercial prospects.1,2 Here, we demonstrate photocathodes with an operational H2 evolution activity over weeks, by integrating a BiOI light absorber into a robust, oxide-based architecture with a graphite paste conductive encapsulant. In this case, the activity towards proton and CO2 reduction is mainly limited by catalyst degradation. We also introduce multiple-pixel devices as an innovative design principle for PEC systems, displaying superior photocurrents, onset biases and stability over corresponding conventional single-pixel devices. Accordingly, PEC tandem devices comprised of multiple-pixel BiOI photocathodes and BiVO4 photoanodes can sustain bias-free water splitting for 240 h, while devices with a Cu92In8 alloy catalyst demonstrate unassisted syngas production.
Date Issued
2022-05-26
Date Acceptance
2022-04-18
Citation
Nature Materials, 2022, 21, pp.864-868
ISSN
1476-1122
Publisher
Nature Research
Start Page
864
End Page
868
Journal / Book Title
Nature Materials
Volume
21
Copyright Statement
© The Author(s), under exclusive licence to Springer Nature Limited 2022. The final publication is available at Springer via https://doi.org/10.1038/s41563-022-01262-w
Sponsor
Royal Academy of Engineering
Royal Academy Of Engineering
Identifier
https://www.nature.com/articles/s41563-022-01262-w
Grant Number
RF\201718\17101
RF\201718\17101
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
Chemistry
Materials Science
Physics
PHOTOANODES
STABILITY
CELLS
Nanoscience & Nanotechnology
Publication Status
Published
Date Publish Online
2022-05-26