Radiation-induced microcrystal shape change as a mechanism of wasteform degradation
File(s)Self Destruction RVDII.docx (2.07 MB)
Accepted version
Author(s)
Ojovan, MI
Burakov, BE
Lee, WE
Type
Journal Article
Abstract
Experiments with actinide-containing insulating wasteforms such as devitrified glasses containing 244 Cm, Ti-pyrochlore, single-phase La-monazite, Pu-monazite ceramics, Eu-monazite and zircon single crystals containing 238 Pu indicate that mechanical self-irradiation-induced destruction may not reveal itself for many years (even decades). The mechanisms causing these slowly-occurring changes remain unknown therefore in addition to known mechanisms of wasteform degradation such as matrix swelling and loss of solid solution we have modelled the damaging effects of electrical fields induced by the decay of radionuclides in clusters embedded in a non-conducting matrix. Three effects were important: (i) electric breakdown; (ii) cluster shape change due to dipole interaction, and (iii) cluster shape change due to polarisation interaction. We reveal a critical size of radioactive clusters in non-conducting matrices so that the matrix material can be damaged if clusters are larger than this critical size. The most important parameters that control the matrix integrity are the radioactive cluster (inhomogeneity) size, specific radioactivity, and effective matrix electrical conductivity. We conclude that the wasteform should be as homogeneous as possible and even electrically conductive to avoid potential damage caused by electrical charges induced by radioactive decay.
Date Issued
2018-02-06
Date Acceptance
2018-01-16
Citation
Journal of Nuclear Materials, 2018, 501, pp.162-171
ISSN
0022-3115
Publisher
Elsevier
Start Page
162
End Page
171
Journal / Book Title
Journal of Nuclear Materials
Volume
501
Copyright Statement
© 2018 Elsevier B.V. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Engineering & Physical Science Research Council (E
Grant Number
EP/L014041/1
Subjects
0912 Materials Engineering
Energy
Publication Status
Published