Facile synthesis of cyanoarenes from quinones by reductive aromatization of cyanohydrin intermediates
File(s) Synlett_accepted version.pdf (326.51 KB)
Accepted version
Author(s)
Gloecklhofer, Florian
Lunzer, Markus
Froehlich, Johannes
Type
Journal Article
Abstract
A novel synthesis of cyanoarenes from quinones by using PCl3 as the reagent for reductive aromatization of cyanohydrin intermediates is reported. In situ IR spectroscopic measurements were conducted to monitor the reactions and to develop a convenient one-pot protocol. 1,4-Dicyanobenzene and 9,10-dicyanoanthracene were prepared by the new procedure.
Date Issued
2015-04-01
Date Acceptance
2015-01-14
Citation
Synlett: accounts and rapid communications in synthetic organic chemistry, 2015, 26 (7), pp.950-952
ISSN
0936-5214
Publisher
Thieme Gruppe
Start Page
950
End Page
952
Journal / Book Title
Synlett: accounts and rapid communications in synthetic organic chemistry
Volume
26
Issue
7
Copyright Statement
© Georg Thieme Verlag Stuttgart · New York
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000352796300017&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
arenes
cyanohydrins
nitriles
quinones
reduction
THIN-FILM TRANSISTORS
FUNCTIONALIZED PENTACENE
ORGANIC TRANSISTORS
CHARGE-TRANSPORT
PERFORMANCE
DERIVATIVES
STABILITY
POLYMER
Publication Status
Published
Date Publish Online
2015-02-19
