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Breaking carbon–fluorine bonds with main group nucleophiles

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Title: Breaking carbon–fluorine bonds with main group nucleophiles
Authors: Coates, G
Rekhroukh, F
Crimmin, MR
Item Type: Journal Article
Abstract: In this Account we describe a series of new reactions that we, and others, have reported that involve the transformation of C–F bonds into C–Mg, C–Al, C–Si, C–Fe and C–Zn bonds. We focus on the use of highly reactive main group nucleophiles and discuss aspects of reaction scope, selectivity and mechanism.
Issue Date: 12-Nov-2019
Date of Acceptance: 15-Oct-2019
URI: http://hdl.handle.net/10044/1/74715
DOI: 10.1055/s-0039-1690738
ISSN: 0936-5214
Publisher: Georg Thieme Verlag KG
Start Page: A
End Page: N
Journal / Book Title: Synlett
Volume: 30
Copyright Statement: © 2019. Thieme. All rights reserved.
Sponsor/Funder: Commission of the European Communities
Commission of the European Communities
The Royal Society
Funder's Grant Number: 677367
745806
RGF\EA\180095
Keywords: Organic Chemistry
0305 Organic Chemistry
0304 Medicinal and Biomolecular Chemistry
Publication Status: Published
Embargo Date: 2020-11-12
Online Publication Date: 2019-11-12
Appears in Collections:Chemistry



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