Heterotrimetallic complexes of iron and ruthenium based on vinyliminium dithiocarboxylate ligands

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Title: Heterotrimetallic complexes of iron and ruthenium based on vinyliminium dithiocarboxylate ligands
Authors: Mognon, L
Richardson, S
Agonigi, G
Bond, T
Marchetti, F
Wilton-Ely, J
Item Type: Journal Article
Abstract: The diiron vinyliminium compounds [Fe2{μ-η1:η3-C(R2) = C(H)C=N(Me)R1}(μ-CO)(CO)(Cp)2]OSO2CF3 (R1 = Xyl = 2,6-C6H3Me2, R2 = Me; R1 = Me, R2 = CO2Me) provide a versatile entry point for many subsequent transformations, such as their reaction with carbon disulfide to provide zwitterionic dithiocarboxylate products. These compounds react with the coordinatively-unsaturated ruthenium vinyl precursors [Ru(CH=CHR3)Cl(CO)(PPh3)2] (R3 = C6H4Me-4, 1-Pyrenyl) to yield heterotrimetallic Fe2Ru compounds, exhibiting vinyl moieties at both iron and ruthenium centres. The emission associated with the pyrenyl unit is enhanced in the diiron vinyliminium ruthenium pyrenyl complex compared to the diethyldithiocarbamate analogue.
Issue Date: 15-Apr-2019
Date of Acceptance: 1-Feb-2019
URI: http://hdl.handle.net/10044/1/67396
DOI: https://dx.doi.org/10.1016/j.jorganchem.2019.02.003
ISSN: 0022-328X
Publisher: Elsevier
Start Page: 9
End Page: 12
Journal / Book Title: Journal of Organometallic Chemistry
Volume: 886
Copyright Statement: © 2019 Elsevier B.V. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor/Funder: The Royal Society
Royal Society
Funder's Grant Number: NF160909
Keywords: 0302 Inorganic Chemistry
0305 Organic Chemistry
0399 Other Chemical Sciences
Organic Chemistry
Publication Status: Published
Online Publication Date: 2019-02-14
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences

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