Peracetic acid: An atom-economical reagent for Pd-catalyzed acetoxylation of C-H bonds

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Title: Peracetic acid: An atom-economical reagent for Pd-catalyzed acetoxylation of C-H bonds
Authors: Mulligan, C
Bagale, S
Newton, O
Parker, J
Hii, KK
Item Type: Journal Article
Abstract: Peracetic acid can be used universally as a source of acetate and an oxidant for the selective acetoxylation of C–H bonds in compounds containing ortho-directing groups, catalyzed by Pd(OAc)2. Compared to previous procedures, where persulfates and PhI(OAc)2 were used, the new protocol provides significant improvements in atom efficiency, product yield, substrate scope, cost, scalability, and environmental impact.
Issue Date: 7-Jan-2019
Date of Acceptance: 11-Dec-2018
URI: http://hdl.handle.net/10044/1/66751
DOI: https://dx.doi.org/10.1021/acssuschemeng.8b05370
ISSN: 2168-0485
Publisher: American Chemical Society
Start Page: 1611
End Page: 1615
Journal / Book Title: ACS Sustainable Chemistry and Engineering
Volume: 7
Issue: 1
Copyright Statement: © 2018 American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Sustainable Chemistry & Engineering, after peer review and technical editing by the publisher. To access the final edited and published work see https://dx.doi.org/10.1021/acssuschemeng.8b05370
Sponsor/Funder: Engineering and Physical Sciences Research Council
Funder's Grant Number: EP/L50547X/1
Keywords: Science & Technology
Physical Sciences
Technology
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Engineering, Chemical
Chemistry
Science & Technology - Other Topics
Engineering
Acetoxylation of C-H bonds
Palladium
Peracetic acid
Atom economy
ANILIDES
ACTIVATION
ARYLATION
FUNCTIONALIZATIONS
ACETANILIDES
OXIDATION
MILD
Publication Status: Published
Embargo Date: 2019-12-11
Online Publication Date: 2018-12-11
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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