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Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly

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Title: Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly
Authors: Wilkinson, L
Massey, E
Yue, T
White, A
Long, N
Item Type: Journal Article
Abstract: Ferrocene-based Lewis bases have found utility as metalloligands in a wide variety of applications. The coordination chemistry of cyanoferrocenes however, is underexplored. Herein, we describe a new synthetic protocol for the generation of cyanoferrocenes. The coordination chemistry of these metalloligands to [Cu(NCMe)4][PF6], [(PPh3)2Cu(NCMe)2][PF6] and [(dppf)Cu(NCMe)2][PF6] salts has been explored, providing crystallographic evidence of cluster and polymeric forms of 1,1′- and 1,2-dicyanoferrocene complexes. The stability of the complexes and ligand dissociation were found to be strongly solvent-dependent.
Issue Date: 7-Jan-2019
Date of Acceptance: 12-Nov-2018
URI: http://hdl.handle.net/10044/1/66346
DOI: https://dx.doi.org/10.1039/c8dt04215b
ISSN: 1477-9234
Publisher: Royal Society of Chemistry
Start Page: 72
End Page: 78
Journal / Book Title: Dalton Transactions
Volume: 48
Issue: 1
Copyright Statement: © The Royal Society of Chemistry 2019
Sponsor/Funder: Engineering & Physical Science Research Council (EPSRC)
Funder's Grant Number: EP/N032977?1
Keywords: Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
SINGLE-MOLECULE MAGNET
MIXED-VALENCE IONS
CRYSTAL-STRUCTURES
COMPLEXES
BEHAVIOR
DPPF
1'-(DIPHENYLPHOSPHINO)-1-CYANOFERROCENE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
RUTHENIUM
AMINATION
0302 Inorganic Chemistry
0399 Other Chemical Sciences
Inorganic & Nuclear Chemistry
Publication Status: Published
Online Publication Date: 2018-11-13
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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