Cross-plane conductance through a graphene/molecular monolayer/Au sandwich

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Title: Cross-plane conductance through a graphene/molecular monolayer/Au sandwich
Authors: Li, B
Famili, M
Pensa, E
Grace, I
Long, NJ
Lambert, C
Albrecht, T
Cohen, LF
Item Type: Journal Article
Abstract: The functionalities offered by single-molecule electrical junctions are yet to be translated into monolayer or few-layer molecular films, where making effective and reproducible electrical contact is one of the challenging bottlenecks. Here we take a significant step in this direction by demonstrating that excellent electrical contact can be made with a monolayer biphenyl-4,4′-dithiol (BPDT) molecular film, sandwiched between gold and graphene electrodes. This sandwich device structure is advantageous, because the current flows through the molecules to the gold substrate in a ‘cross-plane’ manner, perpendicular to the plane of graphene, yielding high-conductance devices. We elucidate the nature of the cross-plane graphene/molecule/Au transport using quantum transport calculations and introduce a simple analytical model, which captures generic features of the current–voltage characteristic. Asymmetry in junction properties results from the disparity in electrode electrical properties, the alignment of the BPDT HOMO–LUMO energy levels and the specific characteristics of the graphene electrode. The experimental observation of scalability of junction properties within the junction area, in combination with a theoretical description of the transmission probability of the thiol–graphene contact, demonstrates that between 10% and 100% of the molecules make contact with the electrodes, which is several orders of magnitude greater than that achieved to date in the literature.
Issue Date: 14-Nov-2018
Date of Acceptance: 25-Sep-2018
URI: http://hdl.handle.net/10044/1/65107
DOI: https://dx.doi.org/10.1039/C8NR06763E
ISSN: 2040-3364
Publisher: Royal Society of Chemistry
Start Page: 19791
End Page: 19798
Journal / Book Title: Nanoscale
Volume: 10
Issue: 42
Copyright Statement: © The Royal Society of Chemistry 2018
Sponsor/Funder: Imperial College Trust
Engineering & Physical Science Research Council (EPSRC)
Funder's Grant Number: N/A
EP/N032977?1
Keywords: Science & Technology
Physical Sciences
Technology
Chemistry, Multidisciplinary
Nanoscience & Nanotechnology
Materials Science, Multidisciplinary
Physics, Applied
Chemistry
Science & Technology - Other Topics
Materials Science
Physics
SINGLE-MOLECULE JUNCTIONS
QUANTUM-INTERFERENCE
ELECTRON-TRANSPORT
BIPHENYL-DITHIOL
CVD-GRAPHENE
CONTACTS
WIRES
FILMS
10 Technology
02 Physical Sciences
03 Chemical Sciences
Publication Status: Published
Online Publication Date: 2018-09-27
Appears in Collections:Physics
Chemistry
Computing
Catalysis and Advanced Materials
Experimental Solid State
Faculty of Natural Sciences



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