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Selective Reduction of CO2 to a Formate Equivalent with Heterobimetallic Gold---Copper Hydride Complexes.

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Title: Selective Reduction of CO2 to a Formate Equivalent with Heterobimetallic Gold---Copper Hydride Complexes.
Authors: Crimmin, MR
Hicken, A
White, AJP
Item Type: Journal Article
Abstract: A series of heterobimetallic complexes containing 3-center,2-electron Au-H-Cu bonds have been prepared from addition of a parent gold hydride to a bent d10 copper(I) fragment. These highly unusual heterobimetallic complexes represent a missing link in the widely investigated series of neutral and cationic coinage metal hydride complexes containing Cu-H-Cu and M-H-M+ moieties (M = Cu, Ag). The well-defined heterobimetallic hydride complexes act as pre-catalysts for the conversion of CO2 to HCO2Bpin using HBpin as a reductant. The selectivity of the heterobimetallic complexes for the catalytic production of a formate equivalent surpasses that of the parent monomeric group 11 complexes.
Issue Date: 4-Oct-2017
Date of Acceptance: 4-Oct-2017
URI: http://hdl.handle.net/10044/1/51851
DOI: https://dx.doi.org/10.1002/anie.201709072
ISSN: 1521-3757
Publisher: Wiley
Start Page: 15127
End Page: 15130
Journal / Book Title: Angewandte Chemie International Edition
Volume: 56
Issue: 47
Copyright Statement: This is the peer reviewed version of the following article: Crimmin, M. R., Hicken, A. and White, A. J. P. (), Selective Reduction of CO2 to a Formate Equivalent with Heterobimetallic Gold---Copper Hydride Complexes. Angew. Chem. Int. Ed.. Accepted Author Manuscript., which has been published in final form at https://dx.doi.org/10.1002/anie.201709072. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
Sponsor/Funder: The Royal Society
The Leverhulme Trust
Funder's Grant Number: UF090149
RPG-2015-248
Keywords: carbon dioxide
copper
gold
heterobimetallic complexes
hydride complexes
Copper
heterobimetallic
hydride
03 Chemical Sciences
Organic Chemistry
Publication Status: Published
Appears in Collections:Chemistry
Faculty of Natural Sciences



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