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Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs

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Title: Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
Authors: Davies, RP
Delmas, L
Horton, PN
White, AJP
Coles, SJ
Lickiss, PD
Item Type: Journal Article
Abstract: A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II).
Issue Date: 6-Nov-2017
Date of Acceptance: 22-Sep-2017
URI: http://hdl.handle.net/10044/1/51321
DOI: https://dx.doi.org/10.1039/c7cc06022j
ISSN: 1359-7345
Publisher: Royal Society of Chemistry
Start Page: 12524
End Page: 12527
Journal / Book Title: Chemical Communications
Volume: 53
Copyright Statement: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keywords: 03 Chemical Sciences
Organic Chemistry
Publication Status: Published
Appears in Collections:Chemistry
Faculty of Natural Sciences



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