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Solvent–dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

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Title: Solvent–dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2
Authors: Brazier, JB
Newton, MA
Barreiro, EM
Adrio, LA
Naya, L
Hii, KM
Item Type: Journal Article
Abstract: The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph]Cl]2 in the solid and solution states are revisited, using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and n-hexylamine, where different deactivation behaviour were observed in toluene, 1,4-dioxane and DMF.
Issue Date: 2-May-2017
Date of Acceptance: 2-May-2017
URI: http://hdl.handle.net/10044/1/48414
DOI: https://dx.doi.org/10.1039/C7DT01019B
ISSN: 1477-9226
Publisher: Royal Society of Chemistry
Start Page: 7223
End Page: 7231
Journal / Book Title: Dalton Transactions
Volume: 46
Copyright Statement: © The Royal Society of Chemistry 2017
Sponsor/Funder: Engineering & Physical Science Research Council (EPSRC)
Funder's Grant Number: EP/G070172/1
Keywords: Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
DENSITY-FUNCTIONAL THEORY
OXIDATIVE ADDITION
PALLADIUM(0) COMPLEXES
COUPLING PROCESSES
HALIDE-COMPLEXES
AMINE BINDING
IN-SITU
LIGAND
REACTIVITY
STABILITY
Palladium
Catalysis
Buchwald-Hartwig cross coupling
Inorganic & Nuclear Chemistry
0302 Inorganic Chemistry
0399 Other Chemical Sciences
Publication Status: Published
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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