Ferrocene- and biferrocene-containing macrocycles towards single molecule electronics

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Title: Ferrocene- and biferrocene-containing macrocycles towards single molecule electronics
Authors: Long, NJ
Albrecht, T
Wilson, L
White, A
Winter, R
Hassenruck, C
Item Type: Journal Article
Abstract: Cyclic multiredox centered systems are currently of great interest, with new compounds being reported and developments made in understanding their behavior. Efficient, elegant, and high-yielding (for macrocyclic species) synthetic routes to two novel alkynyl-conjugated multiple ferrocene- and biferrocene-containing cyclic compounds are presented. The electronic interactions between the individual ferrocene units have been investigated through electrochemistry, spectroelectrochemistry, density functional theory (DFT), and crystallography to understand the effect of cyclization on the electronic properties and structure.
Issue Date: 12-May-2017
Date of Acceptance: 5-Apr-2017
URI: http://hdl.handle.net/10044/1/47888
DOI: https://dx.doi.org/10.1002/anie.201702006
ISSN: 1521-3773
Publisher: Wiley
Start Page: 6838
End Page: 6824
Journal / Book Title: Angewandte Chemie-International Edition
Volume: 56
Issue: 24
Copyright Statement: 2017The Authors.Publishedby Wiley-VCH Verlag GmbH&Co.KGaA.Thisis an openaccessarticleunderthe termsof the CreativeCommonsAttributionLicense,whichpermitsuse, distributionandreproduction in any medium,providedthe originalworkis properlycited
Sponsor/Funder: The Leverhulme Trust
Funder's Grant Number: RPG-2012-754
Keywords: alkynes
electrochemistry
ferrocene
macrocycle
spectroelectrochemistry
Organic Chemistry
03 Chemical Sciences
Publication Status: Published
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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