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Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

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Title: Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.
Authors: Butler, MJ
Crimmin, MR
Item Type: Journal Article
Abstract: The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis.
Issue Date: 3-Jan-2017
Date of Acceptance: 23-Dec-2016
URI: http://hdl.handle.net/10044/1/43712
DOI: https://dx.doi.org/10.1039/c6cc05702k
ISSN: 1364-548X
Publisher: Royal Society of Chemistry
Start Page: 1348
End Page: 1365
Journal / Book Title: Chemical Communications
Volume: 53
Issue: 8
Copyright Statement: © 2017 The Royal Society of Chemistry.
Sponsor/Funder: The Royal Society
Engineering & Physical Science Research Council (EPSRC)
Funder's Grant Number: UF090149
EP/L011514/1
Keywords: Organic Chemistry
03 Chemical Sciences
Publication Status: Published
Conference Place: England
Appears in Collections:Chemistry
Faculty of Natural Sciences



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