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Trajectory of approach of a zinc-hydrogen bond to transition metals

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Title: Trajectory of approach of a zinc-hydrogen bond to transition metals
Authors: Ekkert, O
White, AJ
Crimmin, MR
Item Type: Journal Article
Abstract: Through a dramatic advance in the coordination chemistry of the zinc-hydride bond, we describe the trajectory for the approach of this bond to transition metals. The dynamic reaction coordinate was interrogated through analysis of a series of solid state structures and is one in which the TM-H-Zn angle becomes increasingly acute as the TM-Zn distance decreases. Parallels may be drawn with the oxidative addition of boron-hydrogen and silicon-hydrogen bonds to transition metal centers.
Issue Date: 23-Nov-2016
Date of Acceptance: 1-Nov-2016
URI: http://hdl.handle.net/10044/1/43049
DOI: https://dx.doi.org/10.1002/anie.201608599
ISSN: 1433-7851
Publisher: Wiley
Start Page: 16031
End Page: 16034
Journal / Book Title: Angewandte Chemie - International Edition
Volume: 55
Issue: 52
Sponsor/Funder: Commission of the European Communities
Funder's Grant Number: 677367
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
heterobimetallic complexes
hydrides
zinc
sigma-complexes
RICH BINUCLEAR HYDRIDE
POLYHYDRIDE COMPLEXES
H BONDS
C-H
MOLECULAR-STRUCTURE
OXIDATIVE ADDITION
SIGMA-SILANE
AL-H
ACTIVATION
COORDINATION
σ-complexes
Organic Chemistry
03 Chemical Sciences
Publication Status: Published
Conference Place: Germany
Appears in Collections:Chemistry
Faculty of Natural Sciences



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