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Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)

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Title: Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)
Authors: Crimmin, MR
Butler, MJ
White, AJP
Item Type: Journal Article
Abstract: Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre.
Issue Date: 14-Sep-2015
Date of Acceptance: 14-Sep-2015
URI: http://hdl.handle.net/10044/1/41355
DOI: http://dx.doi.org/10.1039/c5cc07140b
ISSN: 1364-548X
Publisher: Royal Society of Chemistry
Start Page: 15994
End Page: 15996
Journal / Book Title: Chemical Communications
Volume: 51
Issue: 88
Copyright Statement: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sponsor/Funder: The Royal Society
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Commission of the European Communities
Funder's Grant Number: UF090149
EP/L011514/1
EP/K039946/1
655474
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
C-F BOND
ALUMINUM(I) COMPOUND
AL-H
ACTIVATION
RHODIUM
COORDINATION
BORYLATION
COMPLEXES
CLEAVAGE
HYDRODEFLUORINATION
Aluminum
Benzofurans
Fluorobenzenes
Fluorocarbons
Organometallic Compounds
Oxidation-Reduction
Organic Chemistry
03 Chemical Sciences
Publication Status: Published
Appears in Collections:Chemistry
Faculty of Natural Sciences



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