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Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution

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Title: Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution
Authors: Bakewell, C
White, AJ
Crimmin, MR
Item Type: Journal Article
Abstract: Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.
Issue Date: 16-Sep-2016
Date of Acceptance: 6-Aug-2016
URI: http://hdl.handle.net/10044/1/40951
DOI: https://dx.doi.org/10.1021/jacs.6b08104
ISSN: 1520-5126
Publisher: American Chemical Society
Start Page: 12763
End Page: 12766
Journal / Book Title: Journal of the American Chemical Society
Volume: 138
Issue: 39
Copyright Statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, © 2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jacs.6b08104.
Sponsor/Funder: The Royal Society
The Leverhulme Trust
Commission of the European Communities
Funder's Grant Number: UF090149
RPG-2015-248
677367
Keywords: General Chemistry
03 Chemical Sciences
Publication Status: Published
Appears in Collections:Chemistry
Faculty of Natural Sciences



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