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Functionalised [(NHC)Pd(allyl)Cl] complexes: Synthesis, immobilisation and application in cross-coupling and dehalogenation reactions

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Title: Functionalised [(NHC)Pd(allyl)Cl] complexes: Synthesis, immobilisation and application in cross-coupling and dehalogenation reactions
Authors: Collinson, J-M
Wilton-Ely, JDET
Diez-Gonzalez, S
Item Type: Journal Article
Abstract: A novel NHC–palladium(II) (NHC = N-heterocyclic carbene) complex and its immobilised version have been prepared and fully characterised. Optimisation studies led to good catalytic activities in Suzuki-Miyaura cross coupling and chloroarene dehalogenation reactions. Furthermore, the unexpected palladium-mediated transfer hydrogenation of a carbonyl compound is reported.
Issue Date: 9-Sep-2016
Date of Acceptance: 6-Sep-2016
URI: http://hdl.handle.net/10044/1/39953
DOI: https://dx.doi.org/10.1016/j.catcom.2016.09.006
ISSN: 1566-7367
Publisher: Elsevier
Start Page: 78
End Page: 81
Journal / Book Title: Catalysis Communications
Volume: 87
Copyright Statement: © 2016 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).
Keywords: Physical Chemistry
0306 Physical Chemistry (Incl. Structural)
0904 Chemical Engineering
Publication Status: Published
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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