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Homo- and Heteroleptic Copper(I) Complexes with Diazabutadiene Ligands: Synthesis, Solution- and Solid-State Structural Studies

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Title: Homo- and Heteroleptic Copper(I) Complexes with Diazabutadiene Ligands: Synthesis, Solution- and Solid-State Structural Studies
Authors: Zelenay, B
Frutos-Pedreño, R
Markalain-Barta, J
Vega-Isa, E
White, AJP
Diez-Gonzalez, S
Item Type: Journal Article
Abstract: The preparation of novel copper(I) complexes of diazabutadiene (DAB) ligands with aliphatic backbones is reported. [Cu(DABR)2](BF4), [Cu(DABR)(NCMe)2](BF4) and [CuCl(DABR)] are easily synthesised and air-stable. These complexes, which remain scarce in the literature, have been fully characterised, and their behaviour both in the solid state as well as in solution has been studied by means of X-ray crystallography, NMR and UV/Vis spectroscopy.
Issue Date: 29-Aug-2016
Date of Acceptance: 4-Jul-2016
URI: http://hdl.handle.net/10044/1/34753
DOI: https://dx.doi.org/10.1002/ejic.201600620
ISSN: 1434-1948
Publisher: Wiley-VCH Verlag
Start Page: 4649
End Page: 4658
Journal / Book Title: European Journal of Inorganic Chemistry
Volume: 2016
Issue: 28
Copyright Statement: © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. ·This is an open access article under the terms of the Creative CommonsAttribution License, which permits use, distribution and reproduction in anymedium, provided the original work is properly cited.
Sponsor/Funder: Engineering & Physical Science Research Council (EPSRC)
The Royal Society
Funder's Grant Number: EP/K030760/1
RG2015 R1
Keywords: Inorganic & Nuclear Chemistry
0302 Inorganic Chemistry
Publication Status: Published
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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