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Copper(I)-Phosphinite Complexes in Click Cycloadditions: Three-Component Reactions and Preparation of 5-Iodotriazoles

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Title: Copper(I)-Phosphinite Complexes in Click Cycloadditions: Three-Component Reactions and Preparation of 5-Iodotriazoles
Authors: Diez-Gonzalez, S
Lal, S
Perez, J
Crosbie, P
Item Type: Journal Article
Abstract: © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.The remarkable activity displayed by copper(I)–phosphinite complexes of general formula [CuBr(L)] in two challenging cycloadditions is reported: a) the one-pot azidonation/cycloaddition of boronic acids, NaN3, and terminal alkynes; b) the cycloaddition of azides and iodoalkynes. These air-stable catalysts led to very good results in both cases and the expected triazoles could be isolated in pure form under ‘Click-suitable’ conditions.
Issue Date: 13-Jun-2016
Date of Acceptance: 4-Apr-2016
URI: http://hdl.handle.net/10044/1/30858
DOI: https://dx.doi.org/10.1002/cctc.201600234
ISSN: 1867-3880
Publisher: Wiley
Start Page: 2222
End Page: 2226
Journal / Book Title: ChemCatChem
Volume: 8
Issue: 13
Copyright Statement: © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.This is an open access article under the terms of the Creative Commons At-tribution License, which permits use, distribution and reproduction in anymedium, provided the original work is properly cited.
Sponsor/Funder: Engineering & Physical Science Research Council (EPSRC)
The Royal Society
Funder's Grant Number: EP/K030760/1
RG2015 R1
Keywords: Organic Chemistry
Publication Status: Published
Appears in Collections:Chemistry
Catalysis and Advanced Materials
Faculty of Natural Sciences



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