Crimmin, MRMRCrimminButler, MJMJButlerWhite, AJPAJPWhite2016-10-112015-09-142016-10-112015-09-14Chemical Communications, 2015, 51 (88), pp.15994-159961364-548Xhttp://hdl.handle.net/10044/1/41355Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre.This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Science & TechnologyPhysical SciencesChemistry, MultidisciplinaryChemistryC-F BONDALUMINUM(I) COMPOUNDAL-HACTIVATIONRHODIUMCOORDINATIONBORYLATIONCOMPLEXESCLEAVAGEHYDRODEFLUORINATIONAluminumBenzofuransFluorobenzenesFluorocarbonsOrganometallic CompoundsOxidation-ReductionOrganic Chemistry03 Chemical SciencesOxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)Journal Articlehttps://www.dx.doi.org/10.1039/c5cc07140bUF090149EP/L011514/1EP/K039946/1655474