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Analysis of H2O-induced surface degradation in SrCoO3-derivatives and its impact on redox kinetics

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Title: Analysis of H2O-induced surface degradation in SrCoO3-derivatives and its impact on redox kinetics
Authors: Skinner, S
Cavallaro, A
Cali, E
Payne, DJ
Van den Bosch, C
Wilson, G
Kerherve, G
Aguadero, A
Boldrin, P
Item Type: Journal Article
Abstract: Substituted SrCoO3 perovskites have been proposed as promising mixed ionic electronic conductors for a range of applications including intermediate temperature solid oxide fuel cells (IT-SOFCs), electrolysers and thermochemical water splitting reactors for H2 production. In this work we investigate the effect of sample exposure to water in substituted SrCoO3 powders and thin films and correlate it with the degradation of oxygen mobility and kinetics. SrCo0.95Sb0.05O3−δ (SCS) thin films have been deposited on different single crystal substrates by pulsed laser deposition (PLD). After water cleaning and post annealing at 300 °C, the sample surface presented an increase of the SrO-surface species as observed by ex situ X-ray Photoemission Spectroscopy (XPS) analysis. This increase in SrO at the sample surface has also been confirmed by the Low Energy Ion Scattering (LEIS) technique on both SCS thin film and powder. Thermochemical water splitting experiments on SCS and SrCo0.95Mo0.05O3−δ (SCM) powder revealed a phase degradation under water oxidising conditions at high temperature with the formation of the trigonal phase Sr6Co5O15. Transmission Electron Microscopy (TEM) analysis of SCS powder treated with water suggests that this phase degradation could already superficially start at Room Temperature (RT). By isotope exchange depth profile experiments on SCS thin films, we were able to quantify the oxygen diffusivity in this SCS surface decomposed layer (D* = 5.1 × 10−17 cm2 s−1 at 400 °C). In the specific case of bulk powder, the effect of water superficial decomposition translates into a lower oxidation and reduction kinetics as demonstrated by comparative thermogravimetric analysis (TGA) studies.
Issue Date: 7-Oct-2021
Date of Acceptance: 30-Sep-2021
URI: http://hdl.handle.net/10044/1/92548
DOI: 10.1039/D1TA04174F
ISSN: 2050-7488
Publisher: Royal Society of Chemistry
Start Page: 24528
End Page: 24538
Journal / Book Title: Journal of Materials Chemistry A
Volume: 9
Issue: 43
Copyright Statement: © The Royal Society of Chemistry 2021. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sponsor/Funder: Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Funder's Grant Number: EP/P026478/1
Keywords: Science & Technology
Physical Sciences
Chemistry, Physical
Energy & Fuels
Materials Science, Multidisciplinary
Materials Science
0303 Macromolecular and Materials Chemistry
0912 Materials Engineering
0915 Interdisciplinary Engineering
Publication Status: Published
Online Publication Date: 2021-10-07
Appears in Collections:Materials
Earth Science and Engineering
Faculty of Natural Sciences

This item is licensed under a Creative Commons License Creative Commons