Source region geochemistry from unmixing downstream sedimentary elemental compositions

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Title: Source region geochemistry from unmixing downstream sedimentary elemental compositions
Authors: Lipp, A
Item Type: Journal Article
Abstract: The geochemistry of river sediments is routinely used to obtain information about geologic and environmental processes occurring upstream. For example, downstream samples are used to constrain chemical weathering and physical erosion rates upstream, as well as the locations of mineral deposits or contaminant sources. Previous work has shown that, by assuming conservative mixing, the geochemistry of downstream samples can be reliably predicted given a known source region geochemistry. In this study, we tackle the inverse problem and “unmix” the composition of downstream river sediments to produce geochemical maps of drainage basins (i.e., source regions). The scheme is tested in a case study of rivers draining the Cairngorms, UK. The elemental geochemistry of the urn:x-wiley:15252027:media:ggge22639:ggge22639-math-0001 μm fraction of 67 samples gathered from the beds of channels in this region is used to invert for concentrations of major and trace elements upstream. A smoothed inverse problem is solved using the Nelder-Mead optimization algorithm. Predictions of source region geochemistry are assessed by comparing the spatial distribution of 22 elements of different affinities (e.g., Be, Li, Mg, Ca, Rb, U, V) using independent geochemical survey data. The inverse approach makes reliable predictions of the major and trace element concentration in first order river sediments. We suggest this scheme could be a novel means to generate geochemical baselines across drainage basins and within river channels.
Issue Date: Oct-2021
Date of Acceptance: 21-Sep-2021
URI: http://hdl.handle.net/10044/1/92471
DOI: 10.1029/2021GC009838
ISSN: 1525-2027
Publisher: American Geophysical Union
Start Page: 1
End Page: 25
Journal / Book Title: G3: Geochemistry, Geophysics, Geosystems: an electronic journal of the earth sciences
Volume: 22
Issue: 10
Copyright Statement: © 2021. The Authors. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Sponsor/Funder: Natural Environment Research Council [2006-2012]
Funder's Grant Number: NE/L002515/1
Keywords: Geochemistry & Geophysics
02 Physical Sciences
04 Earth Sciences
Publication Status: Published
Open Access location: https://eartharxiv.org/repository/view/2258/
Online Publication Date: 2021-09-30
Appears in Collections:Earth Science and Engineering



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