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Real-time monitoring and hydrodynamic scaling of shear exfoliated graphene

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Title: Real-time monitoring and hydrodynamic scaling of shear exfoliated graphene
Authors: Stafford, J
Uzo, N
Farooq, U
Favero, S
Wang, S
Chen, H-H
L'Hermitte, A
Petit, C
Matar, O
Item Type: Journal Article
Abstract: Shear-assisted liquid exfoliation is a primary candidate for producing defect-free two-dimensional (2D) materials. A range of approaches that delaminate nanosheets from layered precursors in solution have emerged in recent years. Diverse hydrodynamic conditions exist across these methods, and combined with low-throughput, high-cost characterization techniques, strongly contribute to the wide variability in performance and material quality. Nanosheet concentration and production rate are usually correlated against operating parameters unique to each production method, making it difficult to compare, optimize and predict scale-up performance. Here, we reveal the shear exfoliation mechanism from precursor to 2D material and extract the derived hydrodynamic parameters and scaling relationship that are key to nanomaterial output and common to all shear exfoliation processes. Our investigations use conditions created from two different hydrodynamic instabilities—Taylor vortices and interfacial waves—and combine materials characterization, fluid dynamics experiments and numerical simulations. Using graphene as the prototypical 2D material, we find that scaling of concentration of few-layer nanosheets depends on local strain rate distribution, relationship to the critical exfoliation criterion, and precursor residence time. We report a transmission-reflectance method to measure concentration profiles in real-time, using low-cost optoelectronics and without the need to remove the layered precursor material from the dispersion. We show that our high-throughput, in situ approach has broad uses by controlling the number of atomic layers on-the-fly, rapidly optimizing green solvent design to maximize yield, and viewing live production rates. Combining the findings on the hydrodynamics of exfoliation with this monitoring technique, we unlock targeted process intensification, quality control, batch traceability and individually customizable 2D materials on-demand.
Issue Date: 25-Feb-2021
Date of Acceptance: 22-Jan-2021
URI: http://hdl.handle.net/10044/1/86850
DOI: 10.1088/2053-1583/abdf2f
ISSN: 2053-1583
Publisher: IOP Publishing
Start Page: 1
End Page: 17
Journal / Book Title: 2D Materials
Volume: 8
Issue: 2
Copyright Statement: © 2021 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
Sponsor/Funder: Engineering & Physical Science Research Council (E
Funder's Grant Number: EP/R511547/1
Keywords: 0303 Macromolecular and Materials Chemistry
0912 Materials Engineering
1007 Nanotechnology
Publication Status: Published
Online Publication Date: 2021-02-25
Appears in Collections:Chemical Engineering
Faculty of Natural Sciences



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