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Fabrication and aplications of graphene hollow fibre membranes

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Title: Fabrication and aplications of graphene hollow fibre membranes
Authors: Chi, Yunsi
Item Type: Thesis or dissertation
Abstract: Graphene has attracted vast amount of research in the last decade. Attributed to its sp2 hybridisation, graphene is chemically inert, making it an ideal material to be used in extremely harsh conditions. Graphene’s ultra-thin property also makes it an ideal material for membrane separation because permeation is inversely proportional to membrane thickness. While many studies have been carried out on graphene membranes, scaling up remains a key challenge, designing graphene membrane in a geometry which favours module assembly is strongly desired. Furthermore, chemical resistance of metallic membrane can be improved by integrating graphene as a protective barrier. In this thesis, the fabrication and applications of the prepared graphene hollow fibre membranes are explored. Firstly, graphene protected nickel hollow fibre membrane was developed and demonstrated improved chemical resistance compared to the non-protected membrane. Its application was further explored in the production of nanoparticles. Pristine graphene membranes supported on porous ceramic hollow fibre was successfully prepared via the sacrificial layer assisted chemical vapour deposition (CVD) approach. A dense metal sacrificial layer was deposited on the hollow fibre support using electroless plating. After successful graphene growth, this sacrificial layer was removed while the ceramic hollow fibre remained intact to act as the support. Both copper and nickel sacrificial layers were explored. When copper was used, copper dewetting on ceramic surface was observed during high temperature synthesis, which hindered good quality graphene growth. The membrane showed compaction where the permeation flux declined during filtration. Nickel was then investigated to prevent metal dewetting. A dense and continuous nickel sacrificial layer was formed, which was suitable for high-quality CVD graphene synthesis. Finally, pristine graphene membrane supported on ceramic hollow fibre was realised after metal etching, demonstrating reasonable flux and rejection. This study thus presents the successful engineering of graphene hollow fibre membranes suitable for industry scale-up.
Content Version: Open Access
Issue Date: Sep-2019
Date Awarded: Feb-2020
URI: http://hdl.handle.net/10044/1/86163
DOI: https://doi.org/10.25560/86163
Copyright Statement: Creative Commons Attribution NonCommercial Licence
Supervisor: Li, Kang
Livingston, Andrew Guy
Sponsor/Funder: Engineering and Physical Sciences Research Council
Funder's Grant Number: EP/M022250/1
1649713
Department: Chemical Engineering
Publisher: Imperial College London
Qualification Level: Doctoral
Qualification Name: Doctor of Philosophy (PhD)
Appears in Collections:Chemical Engineering PhD theses



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