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Biaryl group 4 metal complexes as non-metallocene catalysts for polyethylene with long chain branching

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Title: Biaryl group 4 metal complexes as non-metallocene catalysts for polyethylene with long chain branching
Authors: Gragert, MM
Tomov, AK
Bettonville, S
Pannier, G
White, AJP
Britovsek, GJP
Item Type: Journal Article
Abstract: A series of biaryl Group 4 complexes with a bidentate and a tridentate pincer ligand have been synthesized and characterized. The complexes have been applied as metallocene analogues for the controlled polymerization of ethylene and the copolymerization of ethylene and 1‐hexene, with a particular focus on the control of the degree of long chain branching in these polymers.
Issue Date: 22-Nov-2020
Date of Acceptance: 1-Nov-2020
URI: http://hdl.handle.net/10044/1/84770
DOI: 10.1002/ejic.202000734
ISSN: 1434-1948
Publisher: Wiley
Start Page: 4088
End Page: 4092
Journal / Book Title: European Journal of Inorganic Chemistry
Volume: 2020
Issue: 43
Copyright Statement: © 2020 The Authors. European Journal of Inorganic Chemistry published by Wiley‐VCH GmbH This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Sponsor/Funder: INEOS Technologies France SAS
Funder's Grant Number: Agreement dated 26 Jan 2009
Keywords: Inorganic & Nuclear Chemistry
0302 Inorganic Chemistry
0399 Other Chemical Sciences
Publication Status: Published
Online Publication Date: 2020-11-05
Appears in Collections:Chemistry
Catalysis and Advanced Materials



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