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Using dicyanoanthracene triflates as superior precursors: modifying properties by sterically hindered aryl substituents

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Title: Using dicyanoanthracene triflates as superior precursors: modifying properties by sterically hindered aryl substituents
Authors: Gloecklhofer, F
Kautny, P
Fritz, P
Stoeger, B
Froehlich, J
Item Type: Journal Article
Abstract: The preparation of 9,10‐dicyanoanthracene triflates is reported. Taking advantage of the high reactivity of these precursors in Suzuki coupling reactions, sterically hindered substituents were introduced. The impact of the substituents on the crystallographic and photophysical properties was investigated. The results highlight the usefulness of the new triflate derivatives and the substituents for the development of 9,10‐dicyanoanthracene‐based materials.
Issue Date: 13-Feb-2017
Date of Acceptance: 5-Dec-2016
URI: http://hdl.handle.net/10044/1/82453
DOI: 10.1002/cptc.201600018
ISSN: 2367-0932
Publisher: Wiley-Blackwell
Start Page: 51
End Page: 55
Journal / Book Title: Chemphotochem
Volume: 1
Issue: 2
Copyright Statement: © 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article, which has been published in final form at https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cptc.201600018. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Keywords: Science & Technology
Physical Sciences
Chemistry, Physical
Chemistry
cross-coupling reactions
cyanides
fluorescence
fused-ring systems
steric hindrance
LIGHT-EMITTING-DIODES
ANTHRACENE-DERIVATIVES
EFFICIENCY
DESIGN
Science & Technology
Physical Sciences
Chemistry, Physical
Chemistry
cross-coupling reactions
cyanides
fluorescence
fused-ring systems
steric hindrance
LIGHT-EMITTING-DIODES
ANTHRACENE-DERIVATIVES
EFFICIENCY
DESIGN
Publication Status: Published
Online Publication Date: 2016-12-05
Appears in Collections:Chemistry