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Large-area CVD MoS2/WS2 heterojunctions as a photoelectrocatalyst for salt water oxidation

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Sherrell et al July 8 2019_MS.docxAccepted version11.32 MBMicrosoft WordView/Open
Sherrell et al- Supporting Information - July5_2019.docxSupporting information7.45 MBMicrosoft WordView/Open
Title: Large-area CVD MoS2/WS2 heterojunctions as a photoelectrocatalyst for salt water oxidation
Authors: Sherrell, PC
Palczynski, P
Sokolikova, MS
Reale, F
Pesci, FM
Och, M
Mattevi, C
Item Type: Journal Article
Abstract: Splitting salt water via sunlight into molecular oxygen and hydrogen for use as fuel or as an energy carrier is a clear pathway toward renewable energy. Monolayer MoS2 and WS2 are promising materials for the energetically demanding water oxidation reaction, absorbing ∼10% of incident light in the visible spectrum and possessing chemical stability and band edges more positive than the oxidation potential of water. A heterostructure of MoS2/WS2 forms a type-II heterojunction, supporting fast separation of the photogenerated charge carriers across the junction. Here, we show the role played by defects in determining the efficiency of the photon-driven oxidation process. By reducing the defects in this material system, it is possible to obtain an incident photon-to-current conversion efficiency (IPCE) of ∼1.6% and a visible-light-driven photocurrent density of 1.7 mA/cm2 for water oxidation. The efficiency is one order of magnitude higher than that of photoelectrocatalytic hydrogen reduction and water oxidation supported by liquid-phase exfoliated transition-metal dichalcogenides (TMDs). This result has been achieved with chemically vapor deposited (CVD) MoS2/WS2 heterojunctions, in the form of 100 μm large flakes assembled to form thin films. The large flakes sizes, compared to liquid-phase exfoliated materials (normally <5 μm), and thus the low edge flake density, and the flakes’ atomically sharp and clean interfaces between the flakes are responsible for reducing charge carrier recombination. These results show a general approach to the scalable synthesis of high-crystal-quality low-dimensional semiconductor photoelectrodes for solar energy conversion systems. It also shows the uniqueness of the CVD synthesis process of these materials, which can lead to high quality materials without the need of any postsynthesis treatments.
Issue Date: 26-Aug-2019
Date of Acceptance: 8-Jul-2019
URI: http://hdl.handle.net/10044/1/71870
DOI: 10.1021/acsaem.9b01008
ISSN: 2574-0962
Publisher: American Chemical Society
Start Page: 5877
End Page: 5882
Journal / Book Title: ACS Applied Energy Materials
Volume: 2
Issue: 8
Copyright Statement: © 2019 American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Energy Materials, after peer review and technical editing by the publisher. To access the final edited and published work see https://dx.doi.org/10.1021/acsaem.9b01008
Sponsor/Funder: Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Commission of the European Communities
The Royal Society
The Royal Society
Funder's Grant Number: EP/K016792/1
EP/L003481/1
EP/M022250/1
660721
UF160539
RGF/EA/180090
Keywords: Science & Technology
Technology
Materials Science, Multidisciplinary
Materials Science
MoS2
WS2
water splitting
photoelectrocatalysis
photoanodes
heterojunctions
CATALYTIC-ACTIVITY
HETEROSTRUCTURES
EVOLUTION
NANOSHEETS
PHOTOOXIDATION
DISULFIDE
GROWTH
Publication Status: Published
Online Publication Date: 2019-07-18
Appears in Collections:Materials
Faculty of Engineering