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A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions
| File | Description | Size | Format | |
|---|---|---|---|---|
 EJOC_Hydroaminarion_Revision2.pdf | Accepted version | 803.94 kB | Adobe PDF | View/Open |
| Title: | A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions |
| Authors: | Zelenay, B Munton, P Tian, X Diez-Gonzalez, S |
| Item Type: | Journal Article |
| Abstract: | The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalysts was also found active in intermolecular aza‐Michael reactions. |
| Issue Date: | 7-Aug-2019 |
| Date of Acceptance: | 26-Jun-2019 |
| URI: | http://hdl.handle.net/10044/1/70911 |
| DOI: | 10.1002/ejoc.201900701 |
| ISSN: | 1099-0690 |
| Publisher: | Wiley |
| Start Page: | 4725 |
| End Page: | 4730 |
| Journal / Book Title: | European Journal of Organic Chemistry |
| Volume: | 2019 |
| Issue: | 29 |
| Copyright Statement: | © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Zelenay, B. , Munton, P. , Tian, X. and Díez-González, S. (2019), A Commercially Available and User‐Friendly Catalyst for Hydroamination Reactions under Technical Conditions. Eur. J. Org. Chem.. Accepted Author Manuscript. doi:10.1002/ejoc.201900701, which has been published in final form at https://dx.doi.org/10.1002/ejoc.201900701 |
| Sponsor/Funder: | The Royal Society |
| Funder's Grant Number: | RG2015 R1 |
| Keywords: | Science & Technology Physical Sciences Chemistry, Organic Chemistry Alkynes Allenes Copper Heterocycles Hydroamination ANTI-MARKOVNIKOV HYDROAMINATION AZA-MICHAEL ADDITION ONE-POT SYNTHESIS INTRAMOLECULAR HYDROAMINATION INTERMOLECULAR HYDROAMINATION ASYMMETRIC-SYNTHESIS EFFICIENT SYNTHESIS TERMINAL ALKYNES AROMATIC-AMINES N-H Organic Chemistry 0305 Organic Chemistry 0304 Medicinal and Biomolecular Chemistry |
| Publication Status: | Published |
| Online Publication Date: | 2019-06-26 |
| Appears in Collections: | Chemistry Catalysis and Advanced Materials Faculty of Natural Sciences |