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Reversible insertion of CO into an aluminium-carbon bond

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Title: Reversible insertion of CO into an aluminium-carbon bond
Authors: Kong, RY
Crimmin, MR
Item Type: Journal Article
Abstract: A [2.2.1] aluminium metallobicycle is capable of reversibly inserting CO to form a [2.2.2] metallobicycle at 100 8C. Computational studies reveal a highly asynchronous, but concerted, transition state for CO insertion. The coordination of CO to aluminium precedes C–C bond formation. The reversible migratory insertion of CO at aluminium thus mimics well-established transition-metal reactivity.
Issue Date: 2-May-2019
Date of Acceptance: 2-May-2019
URI: http://hdl.handle.net/10044/1/70195
DOI: https://dx.doi.org/10.1039/c9cc02818h
ISSN: 1359-7345
Publisher: Royal Society of Chemistry
Start Page: 6181
End Page: 6184
Journal / Book Title: Chemical Communications
Volume: 55
Issue: 44
Copyright Statement: © The Royal Society of Chemistry 2019.
Sponsor/Funder: The Royal Society
Commission of the European Communities
Funder's Grant Number: RGF\EA\180095
Keywords: 03 Chemical Sciences
Organic Chemistry
Publication Status: Published online
Conference Place: England
Online Publication Date: 2019-05-02
Appears in Collections:Chemistry