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Scalable syntheses of well-defined pentadecablock bipolymer and quintopolymer
| File | Description | Size | Format | |
|---|---|---|---|---|
 c8py00565f.pdf | Published version | 1.87 MB | Adobe PDF | View/Open |
| Title: | Scalable syntheses of well-defined pentadecablock bipolymer and quintopolymer |
| Authors: | Carroll, D Constantinou, A Stingelin, N Georgiou, T |
| Item Type: | Journal Article |
| Abstract: | The one-pot syntheses of two pentadeca-(15)-block methacrylate-based amphiphilic copolymers, specifically a bipolymer (AB)7A and a quintopolymer (ABCDE)3, are being reported using a fast and easy to scale up procedure that does not require any intermediate purification steps. Both syntheses were carried out using sequential group transfer polymerisation (GTP) and took under 3.5 h. Amino-containing (DMAEMA, DEAEMA), ether (THFMA, MEGMA) and alkyl (EtMA) methacrylates were used to produce the multiblock copolymers with a final Đ < 1.3. |
| Issue Date: | 7-Jul-2018 |
| Date of Acceptance: | 4-May-2018 |
| URI: | http://hdl.handle.net/10044/1/59834 |
| DOI: | https://dx.doi.org/10.1039/C8PY00565F |
| ISSN: | 1759-9954 |
| Publisher: | Royal Society of Chemistry |
| Start Page: | 3450 |
| End Page: | 3454 |
| Journal / Book Title: | Polymer Chemistry |
| Volume: | 9 |
| Copyright Statement: | © The Royal Society of Chemistry 2018. his article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/) |
| Keywords: | Science & Technology Physical Sciences Polymer Science LIVING ANIONIC-POLYMERIZATION FLOW MICROREACTOR SYSTEM FULL MONOMER CONVERSION MULTIBLOCK COPOLYMERS RAFT POLYMERIZATION THERMORESPONSIVE GELS BLOCK-COPOLYMERS SIDE-GROUP MACROMOLECULES ARCHITECTURE 0303 Macromolecular And Materials Chemistry |
| Publication Status: | Published |
| Online Publication Date: | 2018-05-07 |
| Appears in Collections: | Materials Faculty of Natural Sciences Faculty of Engineering |