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Scalable syntheses of well-defined pentadecablock bipolymer and quintopolymer

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Title: Scalable syntheses of well-defined pentadecablock bipolymer and quintopolymer
Authors: Carroll, D
Constantinou, A
Stingelin, N
Georgiou, T
Item Type: Journal Article
Abstract: The one-pot syntheses of two pentadeca-(15)-block methacrylate-based amphiphilic copolymers, specifically a bipolymer (AB)7A and a quintopolymer (ABCDE)3, are being reported using a fast and easy to scale up procedure that does not require any intermediate purification steps. Both syntheses were carried out using sequential group transfer polymerisation (GTP) and took under 3.5 h. Amino-containing (DMAEMA, DEAEMA), ether (THFMA, MEGMA) and alkyl (EtMA) methacrylates were used to produce the multiblock copolymers with a final Đ < 1.3.
Issue Date: 7-Jul-2018
Date of Acceptance: 4-May-2018
URI: http://hdl.handle.net/10044/1/59834
DOI: https://dx.doi.org/10.1039/C8PY00565F
ISSN: 1759-9954
Publisher: Royal Society of Chemistry
Start Page: 3450
End Page: 3454
Journal / Book Title: Polymer Chemistry
Volume: 9
Copyright Statement: © The Royal Society of Chemistry 2018. his article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/)
Keywords: Science & Technology
Physical Sciences
Polymer Science
LIVING ANIONIC-POLYMERIZATION
FLOW MICROREACTOR SYSTEM
FULL MONOMER CONVERSION
MULTIBLOCK COPOLYMERS
RAFT POLYMERIZATION
THERMORESPONSIVE GELS
BLOCK-COPOLYMERS
SIDE-GROUP
MACROMOLECULES
ARCHITECTURE
0303 Macromolecular And Materials Chemistry
Publication Status: Published
Online Publication Date: 2018-05-07
Appears in Collections:Materials
Faculty of Natural Sciences
Faculty of Engineering