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The mechanisms of hot salt stress corrosion cracking in titanium alloy Ti-6Al-2Sn-4Zr-6Mo
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Title: | The mechanisms of hot salt stress corrosion cracking in titanium alloy Ti-6Al-2Sn-4Zr-6Mo |
Authors: | Joseph, S Lindley, TC Dye, D Saunders, EA |
Item Type: | Journal Article |
Abstract: | Hot salt stress corrosion cracking in Ti 6246 alloy has been investigated to elucidate the chemical mechanisms that occur. Cracking was found to initiate beneath salt particles in the presence of oxidation. The observed transgranular fracture was suspected to be due to hydrogen charging; XRD and high-resolution transmission electron microscopy detected the presence of hydrides that were precipitated on cooling. SEM-EDS showed oxygen enrichment near salt particles, alongside chlorine and sodium. Aluminium and zirconium were also involved in the oxidation reactions. The role of intermediate corrosion products such as Na 2 TiO 3 , Al 2 O 3 , ZrO 2 , TiCl 2 and TiH are discussed. |
Issue Date: | 15-Apr-2018 |
Date of Acceptance: | 16-Feb-2018 |
URI: | http://hdl.handle.net/10044/1/57268 |
DOI: | https://dx.doi.org/10.1016/j.corsci.2018.02.025 |
ISSN: | 0010-938X |
Publisher: | Elsevier |
Start Page: | 169 |
End Page: | 178 |
Journal / Book Title: | Corrosion Science |
Volume: | 134 |
Copyright Statement: | © 2018 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/BY/4.0/) |
Sponsor/Funder: | Engineering & Physical Science Research Council (EPSRC) Rolls-Royce Plc Rolls-Royce Deutschland Ltd & CoKG |
Funder's Grant Number: | EP/K034332/1 PO 4600203311 PO 9900058948 |
Keywords: | Science & Technology Technology Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Materials Science Titanium STEM X-ray diffraction Hot corrosion Hydrogen embrittlement Stress corrosion IMI 834 ALPHA-TITANIUM BETA-TITANIUM MODEL cond-mat.mtrl-sci 0912 Materials Engineering 0905 Civil Engineering 0913 Mechanical Engineering Energy |
Publication Status: | Published |
Online Publication Date: | 2018-02-20 |
Appears in Collections: | Materials Faculty of Natural Sciences Faculty of Engineering |