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Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)
| File | Description | Size | Format | |
|---|---|---|---|---|
 c5cc07140b.pdf | Published version | 1.75 MB | Adobe PDF | View/Open |
| Title: | Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I) |
| Authors: | Crimmin, MR Butler, MJ White, AJP |
| Item Type: | Journal Article |
| Abstract: | Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre. |
| Issue Date: | 14-Sep-2015 |
| Date of Acceptance: | 14-Sep-2015 |
| URI: | http://hdl.handle.net/10044/1/41355 |
| DOI: | http://dx.doi.org/10.1039/c5cc07140b |
| ISSN: | 1364-548X |
| Publisher: | Royal Society of Chemistry |
| Start Page: | 15994 |
| End Page: | 15996 |
| Journal / Book Title: | Chemical Communications |
| Volume: | 51 |
| Issue: | 88 |
| Copyright Statement: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
| Sponsor/Funder: | The Royal Society Engineering & Physical Science Research Council (EPSRC) Engineering & Physical Science Research Council (EPSRC) Commission of the European Communities |
| Funder's Grant Number: | UF090149 EP/L011514/1 EP/K039946/1 655474 |
| Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry C-F BOND ALUMINUM(I) COMPOUND AL-H ACTIVATION RHODIUM COORDINATION BORYLATION COMPLEXES CLEAVAGE HYDRODEFLUORINATION Aluminum Benzofurans Fluorobenzenes Fluorocarbons Organometallic Compounds Oxidation-Reduction Organic Chemistry 03 Chemical Sciences |
| Publication Status: | Published |
| Appears in Collections: | Chemistry Faculty of Natural Sciences |