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Molecular order in buried layers of TbPc2 Single-Molecule Magnets detected by torque magnetometry

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Title: Molecular order in buried layers of TbPc2 Single-Molecule Magnets detected by torque magnetometry
Authors: Perfetti, M
Serri, M
Poggini, L
Mannini, M
Rovai, D
Sainctavit, P
Heutz, SEM
Sessoli, R
Item Type: Journal Article
Abstract: Cantilever torque magnetometry is used to elucidate the orientation of magnetic molecules in thin films. The technique allows depth-resolved investigations by intercalating a layer of anisotropic magnetic molecules in a film of its isotropic analogues. The proof-of-concept is here demonstrated with the single-molecule magnet TbPc2 evidencing also an exceptional long-range templating effect on substrates coated by the organic molecule perylene-3,4,9,10-tetracarboxylic dianhydride.
Issue Date: 27-May-2016
Date of Acceptance: 6-May-2016
URI: http://hdl.handle.net/10044/1/32315
DOI: https://dx.doi.org/10.1002/adma.201600791
ISSN: 1521-4095
Publisher: Wiley-VCH Verlag
Start Page: 6946
End Page: 6951
Journal / Book Title: Advanced Materials
Volume: 28
Issue: 32
Copyright Statement: This is the peer reviewed version of the following article: Perfetti, M., Serri, M., Poggini, L., Mannini, M., Rovai, D., Sainctavit, P., Heutz, S. and Sessoli, R. (2016), Molecular Order in Buried Layers of TbPc2 Single-Molecule Magnets Detected by Torque Magnetometry. Adv. Mater., 28: 6946–6951, which has been published in final form at https://dx.doi.org/10.1002/adma.201600791  This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
Sponsor/Funder: The Royal Society
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Funder's Grant Number: 502008.K617/kk
EP/F039948/1
EP/F04139X/1
EP/H002022/1
Keywords: cantilever torque magnetometry
magnetic anisotropy
synchrotron radiation
terbium phthalocyanine
thin films
Nanoscience & Nanotechnology
02 Physical Sciences
03 Chemical Sciences
09 Engineering
Publication Status: Published
Appears in Collections:Materials
Faculty of Natural Sciences
Faculty of Engineering