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Molecular order in buried layers of TbPc2 Single-Molecule Magnets detected by torque magnetometry
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![]() | Accepted version | 1.26 MB | Adobe PDF | View/Open |
Title: | Molecular order in buried layers of TbPc2 Single-Molecule Magnets detected by torque magnetometry |
Authors: | Perfetti, M Serri, M Poggini, L Mannini, M Rovai, D Sainctavit, P Heutz, SEM Sessoli, R |
Item Type: | Journal Article |
Abstract: | Cantilever torque magnetometry is used to elucidate the orientation of magnetic molecules in thin films. The technique allows depth-resolved investigations by intercalating a layer of anisotropic magnetic molecules in a film of its isotropic analogues. The proof-of-concept is here demonstrated with the single-molecule magnet TbPc2 evidencing also an exceptional long-range templating effect on substrates coated by the organic molecule perylene-3,4,9,10-tetracarboxylic dianhydride. |
Issue Date: | 27-May-2016 |
Date of Acceptance: | 6-May-2016 |
URI: | http://hdl.handle.net/10044/1/32315 |
DOI: | https://dx.doi.org/10.1002/adma.201600791 |
ISSN: | 1521-4095 |
Publisher: | Wiley-VCH Verlag |
Start Page: | 6946 |
End Page: | 6951 |
Journal / Book Title: | Advanced Materials |
Volume: | 28 |
Issue: | 32 |
Copyright Statement: | This is the peer reviewed version of the following article: Perfetti, M., Serri, M., Poggini, L., Mannini, M., Rovai, D., Sainctavit, P., Heutz, S. and Sessoli, R. (2016), Molecular Order in Buried Layers of TbPc2 Single-Molecule Magnets Detected by Torque Magnetometry. Adv. Mater., 28: 6946–6951, which has been published in final form at https://dx.doi.org/10.1002/adma.201600791 This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving. |
Sponsor/Funder: | The Royal Society Engineering & Physical Science Research Council (EPSRC) Engineering & Physical Science Research Council (EPSRC) Engineering & Physical Science Research Council (EPSRC) |
Funder's Grant Number: | 502008.K617/kk EP/F039948/1 EP/F04139X/1 EP/H002022/1 |
Keywords: | cantilever torque magnetometry magnetic anisotropy synchrotron radiation terbium phthalocyanine thin films Nanoscience & Nanotechnology 02 Physical Sciences 03 Chemical Sciences 09 Engineering |
Publication Status: | Published |
Appears in Collections: | Materials Faculty of Natural Sciences Faculty of Engineering |