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Porous organic cage thin films and molecular-sieving membranes

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Title: Porous organic cage thin films and molecular-sieving membranes
Authors: Song, Q
Jiang, S
Hasell, T
Liu, M
Sun, S
Cheetham, AK
Sivaniah, E
Cooper, AI
Item Type: Journal Article
Abstract: Porous organic cage molecules are fabricated into thin films and molecular-sieving membranes. Cage molecules are solution cast on various substrates to form amorphous thin films, with the structures tuned by tailoring the cage chemistry and processing conditions. For the first time, uniform and pinhole-free microporous cage thin films are formed and demonstrated as molecular-sieving membranes for selective gas separation.
Issue Date: 6-Apr-2016
Date of Acceptance: 17-Dec-2015
URI: http://hdl.handle.net/10044/1/29017
DOI: 10.1002/adma.201505688
ISSN: 1521-4095
Publisher: Wiley-VCH Verlag
Start Page: 2629
End Page: 2637
Journal / Book Title: Advanced Materials
Volume: 28
Issue: 13
Copyright Statement: © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Song, Q., Jiang, S., Hasell, T., Liu, M., Sun, S., Cheetham, A. K., Sivaniah, E. and Cooper, A. I. (2016), Porous Organic Cage Thin Films and Molecular-Sieving Membranes. Adv. Mater., 28: 2629–2637, which has been published in final form at https://dx.doi.org/10.1002/adma.201505688
Keywords: Science & Technology
Physical Sciences
Technology
Chemistry, Multidisciplinary
Chemistry, Physical
Nanoscience & Nanotechnology
Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
Chemistry
Science & Technology - Other Topics
Materials Science
Physics
INTRINSIC MICROPOROSITY
FRAMEWORK NANOSHEETS
POLYIMIDE MEMBRANES
GAS SELECTIVITY
POLYMER
PERFORMANCE
SEPARATION
PERMEABILITY
ENHANCEMENT
ACID
molecular crystals
porous organic cages
separation membranes
solution-processing
thin films
Nanoscience & Nanotechnology
02 Physical Sciences
03 Chemical Sciences
09 Engineering
Publication Status: Published
Online Publication Date: 2016-01-22
Appears in Collections:Chemical Engineering
Faculty of Engineering