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A cyclobutanol ring-expansion approach to oxygenated carbazoles: total synthesis of glycoborine, carbazomycin A and carbazomycin B
| File | Description | Size | Format | |
|---|---|---|---|---|
 s-0042-1751411.pdf | Published version | 471.59 kB | Adobe PDF | View/Open |
| Title: | A cyclobutanol ring-expansion approach to oxygenated carbazoles: total synthesis of glycoborine, carbazomycin A and carbazomycin B |
| Authors: | Natho, P Allen, LAT Parsons, PJ |
| Item Type: | Journal Article |
| Abstract: | The transition-metal-free total syntheses of the oxygenated carbazole natural products glycoborine, carbazomycin A and carbazomycin B are reported. The key step involves an NBS-mediated cyclobutanol ring expansion to 4-tetralones for the preparation of the tricyclic carbazole core. |
| Issue Date: | May-2023 |
| Date of Acceptance: | 28-Dec-2022 |
| URI: | http://hdl.handle.net/10044/1/103380 |
| DOI: | 10.1055/s-0042-1751411 |
| ISSN: | 0936-5214 |
| Publisher: | Thieme Gruppe |
| Start Page: | 937 |
| End Page: | 942 |
| Journal / Book Title: | Synlett: accounts and rapid communications in synthetic organic chemistry |
| Volume: | 34 |
| Issue: | 8 |
| Copyright Statement: | © 2023. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by/4.0/) |
| Publication Status: | Published |
| Online Publication Date: | 2023-01-24 |
| Appears in Collections: | Chemistry Faculty of Natural Sciences |
This item is licensed under a Creative Commons License
