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  5. High responsivity circular polarized light detectors based on quasi two-dimensional chiral perovskite films.
 
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High responsivity circular polarized light detectors based on quasi two-dimensional chiral perovskite films.
File(s)
Manuscript ACSNano revised clean.pdf (3.03 MB)
Accepted version
Author(s)
Liu, Tianjun
Shi, Wenda
Tang, Weidong
Liu, Zilu
Schroeder, Bob C
more
Type
Journal Article
Abstract
Circularly polarized light (CPL) has considerable technological potential, from quantum computing to bioimaging. To maximize the opportunity, high performance photodetectors that can directly distinguish left-handed and right-handed circularly polarized light are needed. Hybrid organic-inorganic perovskites containing chiral organic ligands are an emerging candidate for the active material in CPL photodetecting devices, but current studies suggest there to be a trade-off between the ability to differentially absorb CPL and photocurrent responsivity in chiral perovskites devices. Here, we report a CPL detector based on quasi two-dimensional (quasi-2D) chiral perovskite films. We find it is possible to generate materials where the circular dichroism (CD) is comparable in both 2D and quasi-2D films, while the responsivity of the photodetector improves for the latter. Given this, we are able to showcase a CPL photodetector that exhibits both a high dissymmetry factor of 0.15 and a high responsivity of 15.7 A W-1. We believe our data further advocates the potential of chiral perovskites in CPL-dependent photonic technologies.
Date Issued
2022-02-22
Date Acceptance
2022-01-28
Citation
ACS Nano, 2022, 16 (2), pp.2682-2689
URI
http://hdl.handle.net/10044/1/94483
URL
https://pubs.acs.org/doi/10.1021/acsnano.1c09521
DOI
https://www.dx.doi.org/10.1021/acsnano.1c09521
ISSN
1936-0851
Publisher
American Chemical Society
Start Page
2682
End Page
2689
Journal / Book Title
ACS Nano
Volume
16
Issue
2
Copyright Statement
© 2022 American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Nano, after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsnano.1c09521
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/35107990
Grant Number
EP/R00188X/1
Subjects
chiral perovskite
circular dichroism
circularly polarized light
photodetectors
quasi-2D perovskites
Publication Status
Published
Coverage Spatial
United States
Date Publish Online
2022-02-02
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