Gas diffusion layer degradation in proton exchange membrane fuel cells: Mechanisms, characterization techniques and modelling approaches
File(s)Manuscript_revised_06_Sep_without_mark.pdf (1.33 MB)
Accepted version
Author(s)
Pan, Yuwei
Wang, Huizhi
Brandon, Nigel
Type
Journal Article
Abstract
Proton exchange membrane fuel cells (PEMFCs) have been considered as a promising power source for electric vehicles. However, the widespread use of PEMFCs requires a significant improvement in durability. As a key component of PEMFCs, gas diffusion layer (GDL) does not only provide a mechanical support for other fuel cell components, but also governs the mass, heat, and electron transport that directly affect cell performance. In this paper, the latest research progress of GDL durability is reviewed from three aspects: degradation mechanisms, experimental methods, and modelling approaches. The six degradation modes of GDLs, namely chemical oxidation, electrochemical carbon corrosion, freezing/thawing, mechanical degradation, material dissolution and erosion by gas flow are discussed under different cell operating conditions. Experimental techniques, including the long-term and accelerated stress tests (AST) and methods for measuring property deterioration are then introduced. Several AST protocols have been developed to decouple the above degradation modes, but few have tried to relate these tests with GDL degradation in practice. Modelling approaches relating to GDL degradation are also covered. Although various types of models have been developed for multiple purposes, a complete model from the mechanistic level to the cell performance is still missing.
Date Issued
2021-11-01
Date Acceptance
2021-09-23
Citation
Journal of Power Sources, 2021, 513
ISSN
0378-7753
Publisher
Elsevier
Journal / Book Title
Journal of Power Sources
Volume
513
Copyright Statement
© 2021 Elsevier B.V. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Engineering & Physical Science Research Council (E
Grant Number
EP/P024807/1
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Electrochemistry
Energy & Fuels
Materials Science, Multidisciplinary
Chemistry
Materials Science
Proton exchange membrane fuel cells
Gas diffusion layer
Durability
Characterization
Degradation model
OPEN-CIRCUIT VOLTAGE
EFFECTIVE TRANSPORT-PROPERTIES
CATHODE CATALYST LAYER
MICRO-POROUS LAYER
LIQUID-WATER
THERMAL-CONDUCTIVITY
CONTACT RESISTANCE
CARBON CORROSION
COLD-START
IN-SITU
03 Chemical Sciences
09 Engineering
Energy
Publication Status
Published
Article Number
ARTN 230560
Date Publish Online
2021-09-29