Degradation diagnostics for Li4Ti5O12-based lithium ion capacitors: insights from a physics-based model
Author(s)
Madabattula, G
Wu, Billy
Marinescu, Monica
Offer, Gregory
Type
Journal Article
Abstract
Lithium ion capacitors are an important energy storage technology, providing the optimum combination of power, energy and cycle life for high power applications. However, there has been minimal work on understanding how they degrade and how this should influence their design. In this work, a 1D electrochemical model of a lithium ion capacitor with activated carbon (AC) as the positive electrode and lithium titanium oxide (LTO) as the negative electrode is used to simulate the consequences of different degradation mechanisms in order to explore how the capacity ratio of the two electrodes affects degradation. The model is used to identify and differentiate capacity loss due to loss of active material (LAM) in the lithiated and de-lithiated state and loss of lithium inventory (LLI). The model shows that, with lower capacity ratios (AC/LTO), LAM in the de-lithiated state cannot be identified as the excess LTO in the cell balances the capacity loss. Cells with balanced electrode capacity ratios are therefore necessary to differentiate LAM in lithiated and de-lithiated states and LLI from each other. We also propose in situ diagnostic techniques which will be useful to optimize a LIC's design. The model, built in COMSOL, is available online.
Date Issued
2020-02-26
Date Acceptance
2020-02-26
Citation
Journal of The Electrochemical Society, 2020, 167 (4)
ISSN
0013-4651
Publisher
Electrochemical Society
Journal / Book Title
Journal of The Electrochemical Society
Volume
167
Issue
4
Copyright Statement
© 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited. This is an open accessarticle distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY,http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.
Sponsor
Innovate UK
Identifier
https://iopscience.iop.org/article/10.1149/1945-7111/ab7655
Grant Number
102655
Subjects
0303 Macromolecular and Materials Chemistry
0306 Physical Chemistry (incl. Structural)
0912 Materials Engineering
Energy
Publication Status
Published
Article Number
ARTN 043503
Date Publish Online
2020-02-26