An electro-chemo-mechanical framework for predicting hydrogen uptake in metals due to aqueous electrolytes
File(s)Hydrogen_diffusion_Electrolyte.pdf (4.56 MB)
Working paper
OA Location
Author(s)
Hageman, T
Martínez-Pañeda, E
Type
Working Paper
Abstract
We present a theoretical and numerical scheme that enables quantifying hydrogen ingress in metals for arbitrary environments and defect geometries. This is achieved by explicitly resolving the electrochemical behaviour of the electrolyte, the hydrogen and corrosion reactions, the kinetics of surface adsorption, and hydrogen uptake, diffusion and trapping in mechanically-deforming solids. This new framework is used to produce maps that relate the absorbed hydrogen with the applied potential, specimen geometry and fluid velocity. We also present simplified versions of our generalised model, and benchmark predictions of these and other existing models against the generalised electro-chemo-mechanical results, establishing regimes of validity.
Date Issued
2022-09-18
Date Acceptance
2022-09-18
Citation
Corrosion Science, 2022, 208
ISSN
0010-938X
Publisher
Elsevier
Journal / Book Title
Corrosion Science
Volume
208
Copyright Statement
© 2022 The Author(s)
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Identifier
http://arxiv.org/abs/2209.08635v1
Grant Number
EP/V009680/1
Subjects
physics.chem-ph
physics.chem-ph
cs.CE
physics.app-ph
Publication Status
Published
Article Number
110681
Date Publish Online
2022-09-28