Modelling of Supercapacitors: Factors Influencing Performance
File(s)J. Electrochem. Soc.-2016-Kroupa-A2475-87.pdf (1.58 MB)
Published version
OA Location
Author(s)
Kroupa, M
Offer, GJ
Kosek, J
Type
Journal Article
Abstract
The utilizable capacitance of Electrochemical Double Layer Capacitors (EDLCs) is a function of the frequency at which they are operated and this is strongly dependent on the construction and physical parameters of the device. We simulate the dynamic behavior of an EDLC using a spatially resolved model based on the porous electrode theory. The model of Verbrugge and Liu (J. Electrochem. Soc. 152, D79 (2005)) was extended with a dimension describing the transport into the carbon particle pores. Our results show a large influence of the electrode thickness (Le), separator thickness (Ls) and electrolyte conductivity (κ) on the performance of EDLCs. In agreement with experimental data, the time constant was an increasing function of Le and Ls and a decreasing function of κ. The main limitation was found to be on the scale of the whole cell, while transport into the particles became a limiting factor only if the particle size was unrealistically large. The results were generalized into a simplified relation allowing for a quick evaluation of performance for the design of new devices. This work provides an insight into the performance limitation of EDLCs and identifies the critical parameters to consider for both systems engineers and material scientists.
Date Issued
2016-09-12
Date Acceptance
2016-08-31
Citation
Journal of the Electrochemical Society, 2016, 163 (10), pp.A2475-A2487
ISSN
0013-4651
Publisher
Electrochemical Society
Start Page
A2475
End Page
A2487
Journal / Book Title
Journal of the Electrochemical Society
Volume
163
Issue
10
Copyright Statement
© The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons
Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/),
which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any
way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0081613jes]
All rights reserved.
Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/),
which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any
way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0081613jes]
All rights reserved.
Subjects
Energy
0303 Macromolecular And Materials Chemistry
0306 Physical Chemistry (Incl. Structural)
0912 Materials Engineering
Publication Status
Published
Date Publish Online
2016-09-12