Exploring the potential of clumped isotope thermometry on coccolith-rich sediments as a sea surface temperature proxy
File(s)Drury_et_al-2016-Geochemistry,_Geophysics,_Geosystems.pdf (12.91 MB)
Published version
Author(s)
Drury, AJ
John, CM
Type
Journal Article
Abstract
Understanding past changes in sea surface temperatures (SSTs) is crucial; however, existing proxies for reconstructing past SSTs are hindered by unknown ancient seawater composition (foraminiferal Mg/Ca and δ18O), or reflect subsurface temperatures (TEX86) or have a limited applicable temperature range (Uk'37). We examine clumped isotope (Δ47) thermometry to fossil coccolith-rich material as an SST proxy, as clumped isotopes are independent of original seawater composition and applicable to a wide temperature range and coccolithophores are widespread and dissolution resistant. The Δ47-derived temperatures from <63, <20, <10 and 2-5 μm size fractions of two equatorial Pacific late Miocene-early Pliocene sediment samples (c1; c2) range between ∼18-29°C, with c1 temperatures consistently above c2. Removing the >63 μm fraction removes most non-mixed layer components; however, the Δ47-derived temperatures display an unexpected slight decreasing trend with decreasing size fraction. This unexpected trend could partly arise because larger coccoliths (5-12 μm) are removed during the size fraction separation process. The c1 and <63 μm c2 Δ47-derived temperatures are comparable to concurrent Uk'37 SSTs. The <20, <10 and 2-5 μm c2 Δ47-derived temperatures are consistently cooler than expected. The Δ47-Uk'37 temperature offset is probably caused by abiotic/diagenetic calcite present in the c2 2-5 μm fraction (∼53% by area), which potentially precipitated at bottom water temperatures of ∼6°C . Our results indicate that clumped isotopes on coccolith-rich sediment fractions have potential as an SST proxy, particularly in tropical regions, providing that careful investigation of the appropriate size fraction for the region and timescale is undertaken.
Date Issued
2016-10-01
Date Acceptance
2016-09-27
Citation
G3: Geochemistry, Geophysics, Geosystems: an electronic journal of the earth sciences, 2016, 17 (10), pp.4092-4104
ISSN
1525-2027
Publisher
American Geophysical Union
Start Page
4092
End Page
4104
Journal / Book Title
G3: Geochemistry, Geophysics, Geosystems: an electronic journal of the earth sciences
Volume
17
Issue
10
Copyright Statement
© 2016 American Geophysical Union. All Rights Reserved.
Identifier
https://agupubs.onlinelibrary.wiley.com/doi/full/10.1002/2016GC006459
Subjects
Science & Technology
Physical Sciences
Geochemistry & Geophysics
CARBONATE MINERALS
EQUATORIAL PACIFIC
C-13-O-18 BONDS
LATE MIOCENE
FORAMINIFERA
CALCITE
CALCIFICATION
FRACTIONATION
GEOCHEMISTRY
CALIBRATION
02 Physical Sciences
04 Earth Sciences
Geochemistry & Geophysics
Publication Status
Published
Date Publish Online
2016-09-29