Self-assembly of a porous metallo-[5]rotaxane
File(s)d0cc04780e.pdf (3.85 MB)
Published online
Author(s)
Wong, Kevin
Hoyas Perez, Nadia
White, Andrew
Lewis, James
Type
Journal Article
Abstract
A mechanically interlocked [2]rotaxane is reported incorporating a ditopic ligand moiety as one of the stoppers. Upon complexation with palladium(II) ions a metallo-[5]rotaxane was formed with a porous Pd2L4 metal–organic cage at the core of the structure. This proof-of-principle system precedes work towards the construction of metal organic polyhedra with switchable mechano-chemical properties.
Date Issued
2020-08-04
Date Acceptance
2020-07-28
Citation
Chemical Communications, 2020, 72 (56), pp.10453-10456
ISSN
1359-7345
Publisher
Royal Society of Chemistry
Start Page
10453
End Page
10456
Journal / Book Title
Chemical Communications
Volume
72
Issue
56
Copyright Statement
©The Royal Society of Chemistry 2020. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/)
License URL
Sponsor
The Royal Society
Identifier
https://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC04780E#!divAbstract
Grant Number
RG170321
Subjects
Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
ACTIVE-TEMPLATE SYNTHESIS
COORDINATION CAGES
CLICK
CONSTRUCTION
MACROCYCLES
STRATEGIES
FRAMEWORKS
ROTAXANES
DISCRETE
POLYMERS
Organic Chemistry
03 Chemical Sciences
Publication Status
Published
Date Publish Online
2020-08-04