Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes
File(s)
Author(s)
Prades, A
Fernández, M
Pike, SD
Willis, MC
Weller, AS
Type
Journal Article
Abstract
A Rh-catalyst system based on the asymmetric ligand tBu2PCH2P(o-C6H4OMe)2 is reported that allows for the hydroacylation of challenging internal alkenes with β-substituted aldehydes. Mechanistic studies point to the stabilizing role of both excess alkene and the OMe-group.
Date Issued
2015-06-09
Date Acceptance
2015-04-08
Citation
Angewandte Chemie - International Edition, 2015, 54 (29), pp.8520-8524
ISSN
1433-7851
Publisher
Wiley
Start Page
8520
End Page
8524
Journal / Book Title
Angewandte Chemie - International Edition
Volume
54
Issue
29
Copyright Statement
© 2015 The Authors. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
License URL
Subjects
Organic Chemistry
03 Chemical Sciences
Publication Status
Published