Divergent reactivity of platinum(II) and palladium(II) methylperoxo complexes and the formation of an unusual hemi-aminal complex

Petersen, AR; White, AJ; Britovsek, GJ

doi:https://www.dx.doi.org/10.1039/c6dt01691j

File(s)

BriDaltonmanuscREV.pdf (686.84 KB)

Accepted version

Author(s)

Petersen, AR

White, AJ

Britovsek, GJ

Type

Journal Article

Abstract

The 6,6′′-diaminoterpyridine palladium(II) methylperoxo complex eliminates methyl hydroperoxide and reacts with acetone to form a novel hemi-aminal palladium complex, whereas the analogous platinum(II) complex generates formaldehyde and a platinum(II) hydroxo complex.

Date Issued

2016-05-30

Date Acceptance

2016-05-27

Citation

Dalton Transactions, 2016, 45 (37), pp.14520-14523

URI

http://hdl.handle.net/10044/1/33906

DOI

https://www.dx.doi.org/10.1039/c6dt01691j

ISSN

1477-9226

Publisher

Royal Society of Chemistry

Start Page

14520

End Page

14523

Journal / Book Title

Dalton Transactions

Volume

45

Issue

37

Copyright Statement

Subjects

Inorganic & Nuclear Chemistry

Inorganic Chemistry

Other Chemical Sciences

Publication Status

Published