Polarisation dependence of the squash mode in the extreme low frequency vibrational region of single walled carbon nanotubes
File(s)quirke.pdf (1.38 MB)
Published version
Author(s)
Shen, Y
Quirke, N
Zerulla, D
Type
Journal Article
Abstract
There is considerable interest in the vibrational modes of carbon nanotubes as they can be used to determine interaction potentials. In particular, theory predicts the appearance of so called squash modes (SMs, with E 2 g symmetry representation) at very low frequencies. These SMs are expected to be extremely sensitive to environmental changes and thus ideal as nanoscale probes. Here, we report clear experimental evidence for the existence of SMs of ordered, dry, single walled carbon nanotube (SWNT) arrays with peaks as close as 18 cm−1 to the laser excitation. Furthermore, we confirm the theoretical predictions regarding the angular and polarisation dependent variations of the SM's intensity with respect to the excitation. Additionally, using both SM and radial breathing mode data, we unambiguously assign the chirality and diameter of the SWNTs in our sample.
Date Issued
2015-05-18
Date Acceptance
2015-05-07
Citation
Applied Physics Letters, 2015, 106 (20)
ISSN
1077-3118
Publisher
American Institute of Physics (AIP)
Journal / Book Title
Applied Physics Letters
Volume
106
Issue
20
Copyright Statement
Copyright © 2015 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Appl. Phys. Lett. 106, 201902 (2015) and may be found at http://scitation.aip.org/content/aip/journal/apl/106/20/10.1063/1.4921402
Subjects
Science & Technology
Physical Sciences
Physics, Applied
Physics
RAMAN-SPECTROSCOPY
SENSORS
Publication Status
Published
Article Number
ARTN 201902