The importance of transport phenomena on the flow synthesis of monodispersed sharp blue-emitting perovskite CsPbBr3 nanoplatelets
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Published version
Author(s)
Type
Journal Article
Abstract
This work demonstrates the importance of transport phenomena on the synthesis of halide perovskite nanoplatelets. Illustrated herein for CsPbBr3, we demonstrate the need for fast and homogeneous mixing to achieve monodispered crystals, in this case with sharp blue emission. The modularity of our synthesis method, combining fluid dynamic simulations, bespoke 3D flow reactors and on-line measurements (UV-vis absorbance and photoluminescence) reveals fundamental understanding about the growth of these perovskite nano-materials, which in turn leads to superlative size reducibility (2.2 ±0.3 nm) and properties (sharp blue emission at 472 nm wavelength, and PLQY 24.5±0.4%). The counterpart conventional hot injection batch synthesis with the same precursors, conditions and reaction temperature yields a product with PL at 501 nm with large batch to batch variations. Understanding the dynamics of the synthesis in the very early stages (within the first 100-300 ms) shows that mixing of the precursors plays a key role not only during the nucleation step, as previously believed, but also during the growth stage. Such fluid properties can be easily predicted in purposefully designed 3D microreactors to provide a consistent and steady output capable of fulfilling the large demand of blue light emitters for a variety of applications.
Date Issued
2023-01-01
Date Acceptance
2022-08-20
Citation
Chemical Engineering Journal, 2023, 451 (Part 4), pp.1-9
ISSN
1385-8947
Publisher
Elsevier
Start Page
1
End Page
9
Journal / Book Title
Chemical Engineering Journal
Volume
451
Issue
Part 4
Copyright Statement
© 2022 The Authors. Published by Elsevier B.V. this Pre-Proof version is available open access under a CC-BY Attribution License (https://creativecommons.org/licenses/by/4.0/)
License URL
Identifier
https://www.sciencedirect.com/science/article/pii/S1385894722042334?via%3Dihub
Subjects
Science & Technology
Technology
Engineering, Environmental
Engineering, Chemical
Engineering
Perovskite crystals
Mixing
Microreactors
Growth rate
CESIUM LEAD HALIDE
COLLOIDAL CH3NH3PBX3 X
MICROFLUIDIC PLATFORM
SILVER NANOPARTICLES
CAPPING LIGANDS
NANOCRYSTALS
LUMINESCENT
SHAPE
BR
NUCLEATION
Chemical Engineering
0904 Chemical Engineering
0905 Civil Engineering
0907 Environmental Engineering
Publication Status
Published
Article Number
ARTN 138752
Date Publish Online
2022-08-24